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Material Safety Data Sheet

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Abstract: by ACGIH, 3 (Not classifiable for humans.) by IARC [Toluene]. Classified 2B (Possible for ... by ACGIH [Titanium dioxide]. Classified A4 (Not. classifiable for humans or animals.) by ...
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Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).
Material Safety Data Sheet
DAR
1 . Product and company identification
Common name : DAR
Material uses : Not available.
Supplier/Manufacturer : San Leandro Color
555 Est 14 th Street
San Leandro, CA
USA, 94577
In case of emergency : CHEMTREC, U.S. : (800) 424-9300 International: (703) 527-3887
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 11/15/2006
2 . Hazards identification
Physical state : Liquid. (Aerosol.)
Odor : Solvent.
Hazard status : This material is classified hazardous under OSHA regulations in the United States, the
WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 in
Mexico.
Emergency overview : WARNING !
EXTREMELY FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FIRE.
CONTENTS UNDER PRESSURE.
CANCER HAZARD.
CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
BIRTH DEFECT HAZARD.
CONTAINS MATERIAL WHICH CAN CAUSE BIRTH DEFECT.
HARMFUL IF INHALED OR SWALLOWED.
CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS:
BLOOD, KIDNEYS, LUNGS, LIVER, PERIPHERAL NERVOUS SYSTEM,
GASTROINTESTINAL TRACT, RESPIRATORY TRACT, SKIN, CENTRAL NERVOUS
SYSTEM, EYE, LENS OR CORNEA, NOSE, SINUSES, THROAT.
Do not ingest. Avoid prolonged contact with eyes, skin and clothing. Avoid breathing
vapor or mist. Keep away from heat, sparks and flame. Keep container closed. Use only
with adequate ventilation. Wash thoroughly after handling. Risk of cancer depends o
duration and level of exposure. Avoid exposure during pregnancy.
Routes of entry : Dermal contact. Eye contact. Inhalation.
Potential acute health effects
Eyes : Irritating to eyes.
Skin : Irritating to skin. May cause sensitization by skin contact. May be harmful if absorbed
through skin.
Inhalation : Harmful by inhalation. Irritating to respiratory system.
Ingestion : Harmful if swallowed.
Potential chronic health : Carcinogenic effects: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3
effects (Not classifiable for humans.) by IARC [Toluene]. Classified 2B (Possible for humans.) by
IARC [Titanium dioxide]. Classified None. by NIOSH [Titanium dioxide]. Classified A4 (Not
classifiable for humans or animals.) by ACGIH [Titanium dioxide]. Classified A4 (Not
classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC
[Xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by
IARC [Ethylbenzene]. Classified None. by NIOSH [Ethylbenzene]. Classified + (Proven.)
by NIOSH [Carbon Black]. Classified 2B (Possible for humans.) by IARC [Carbon Black].
Date of issue : 11/15/2006 Page: 1/11
DAR
Classified A4 (Not classifiable for humans or animals.) by ACGIH [Carbon Black].
Mutagenic effects Not available.
:
Teratogenic effects: Not available.
Medical conditions : Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or
aggravated by over- prolonged exposure to the substance can produce lung damage. Repeated or prolonged
exposure contact with spray or mist may produce chronic eye irritation and severe skin irritation.
Repeated or prolonged exposure to the substance can produce target organ damage.
See toxicological information (section 11)
3 . Composition/information on ingredients
United States
Name CAS number %
Difluoroethane 75-37-6 30 - 60
Toluene 108-88-3 10 - 30
Titanium dioxide 13463-67-7 10 - 30
Xylene 1330-20-7 10 - 30
Heptan-2-one 110-43-0 1-5
Ethylbenzene 100-41-4 1-5
Carbon Black 1333-86-4 1-5
Methyl ethyl ketone 78-93-3 1-5
Stoddard Solvent 8052-41-3 1-5
Solvent naphtha (petroleum), light aromatic 64742-95-6 1-5
Canada
Name CAS number %
Difluoroethane 75-37-6 30 - 60
Toluene 108-88-3 10 - 30
Titanium dioxide 13463-67-7 10 - 30
Xylene 1330-20-7 10 - 30
Heptan-2-one 110-43-0 1-5
Ethylbenzene 100-41-4 1-5
Carbon Black 1333-86-4 1-5
Methyl ethyl ketone 78-93-3 1-5
Stoddard Solvent 8052-41-3 1-5
Solvent naphtha (petroleum), light aromatic 64742-95-6 1-5
Mexico
Classification
Name UN number IDLH H F R Special CAS number %
Difluoroethane UN1030 - 1 4 0 75-37-6 30 - 60
Toluene UN1294 500 ppm 2 3 0 108-88-3 10 - 30
Xylene UN1307 900 ppm 2 3 0 1330-20-7 10 - 30
Titanium dioxide Not 5000 mg/m3 0 0 0 13463-67-7 10 - 30
regulated.
Heptan-2-one UN1110 800 ppm 1 2 0 110-43-0 1-5
Ethylbenzene UN1175 800 ppm 2 3 0 100-41-4 1-5
Carbon Black Not 1750 mg/m3 2 0 0 1333-86-4 1-5
regulated.
Methyl ethyl ketone UN1193 3000 ppm 1 3 0 78-93-3 1-5
Stoddard Solvent UN1268 20000 mg/m3 1 2 0 8052-41-3 1-5
Date of issue : 11/15/2006 Page: 2/11
DAR
4 . First aid measures
Eye contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 20 minutes. Get medical attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Get
medical attention immediately.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
Ingestion : Do not induce vomiting. Never give anything by mouth to an unconscious person. Get
medical attention immediately.
Notes to physician : No specific antidote. Medical staff must contact Poison Control Center.
5 . Fire-fighting measures
Flammability of the product : Flammable.
Products of combustion : These products are carbon oxides, halogenated compounds, hydrogen fluoride. Some
metallic oxides.
Extinguishing media
Suitable : Use dry chemical, carbon dioxide, water spray (fog) or foam.
Not suitable : Do not use water jet.
Special exposure hazards : Flammable liquid and vapor. Vapor may cause flash fire. Vapors may accumulate in low
or confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
6 . Accidental release measures
Personal precautions : Immediately contact emergency personnel. Eliminate all ignition sources. Keep
unnecessary personnel away. Use suitable protective equipment. Do not touch or walk
through spilled material.
Environmental precautions : Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and
sewers.
Methods for cleaning up : If emergency personnel are unavailable, contain spilled material. For small spills, add
absorbent (soil may be used in the absence of other suitable materials) and use a non-
sparking or explosion-proof means to transfer material to a sealable, appropriate
container for disposal. For large spills, dike spilled material or otherwise contain material
to ensure runoff does not reach a waterway. Place spilled material in an appropriate
container for disposal.
7 . Handling and storage
Handling : Do not ingest. Avoid contact with eyes, skin and clothing. Keep container closed. Use
only with adequate ventilation. Avoid breathing vapor or mist. Keep away from heat,
sparks and flame. To avoid fire or explosion, dissipate static electricity during transfer by
grounding and bonding containers and equipment before transferring material. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Wash
thoroughly after handling.
Storage : Store in a segregated and approved area. Keep container in a cool, well-ventilated area.
Keep container tightly closed and sealed until ready for use. Avoid all possible sources of
ignition (spark or flame).
Date of issue : 11/15/2006 Page: 3/11
DAR
8 . Exposure controls/personal protection
United States
Product name Exposure limits
Difluoroethane AIHA WEEL (United States, 1/2004).
TWA: 1000 ppm 8 hour(s). Form: All forms
Toluene ACGIH TLV (United States, 1/2005). Skin
TWA: 188 mg/m3 8 hour(s). Form: All forms.
TWA: 50 ppm 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001).
STEL: 560 mg/m3 15 minute(s). Form: All forms.
STEL: 150 ppm 15 minute(s). Form: All forms.
TWA: 375 mg/m3 10 hour(s). Form: All forms.
TWA: 100 ppm 10 hour(s). Form: All forms.
OSHA PEL Z2 (United States, 8/1997).
AMP: 500 ppm 10 minute(s). Form: All forms.
TWA: 200 ppm 8 hour(s). Form: All forms.
Titanium dioxide ACGIH TLV (United States, 1/2005).
TWA: 10 mg/m3 8 hour(s). Form: All forms.
OSHA PEL (United States, 8/1997).
TWA: 15 mg/m3 8 hour(s). Form: Total dust
Xylene ACGIH TLV (United States, 1/2005).
STEL: 651 mg/m3 15 minute(s). Form: All forms.
STEL: 150 ppm 15 minute(s). Form: All forms.
TWA: 434 mg/m3 8 hour(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
OSHA PEL (United States, 8/1997).
TWA: 435 mg/m3 8 hour(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
Heptan-2-one NIOSH REL (United States, 12/2001).
TWA: 465 mg/m3 10 hour(s). Form: All forms.
TWA: 100 ppm 10 hour(s). Form: All forms.
OSHA PEL (United States, 8/1997).
TWA: 465 mg/m3 8 hour(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
ACGIH TLV (United States, 1/2005).
TWA: 233 mg/m3 8 hour(s). Form: All forms.
TWA: 50 ppm 8 hour(s). Form: All forms.
Ethylbenzene ACGIH TLV (United States, 1/2005).
STEL: 125 ppm 15 minute(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001).
STEL: 545 mg/m3 15 minute(s). Form: All forms.
STEL: 125 ppm 15 minute(s). Form: All forms.
TWA: 435 mg/m3 10 hour(s). Form: All forms.
TWA: 100 ppm 10 hour(s). Form: All forms.
OSHA PEL (United States, 8/1997).
TWA: 435 mg/m3 8 hour(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
Carbon Black ACGIH TLV (United States, 1/2005).
TWA: 3.5 mg/m3 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001).
TWA: 3.5 mg/m3 10 hour(s). Form: All forms.
OSHA PEL (United States, 8/1997).
TWA: 3.5 mg/m3 8 hour(s). Form: All forms.
Methyl ethyl ketone ACGIH TLV (United States, 1/2005).
STEL: 885 mg/m3 15 minute(s). Form: All forms.
STEL: 300 ppm 15 minute(s). Form: All forms.
TWA: 590 mg/m3 8 hour(s). Form: All forms.
Date of issue : 11/15/2006 Page: 4/11
DAR
TWA: 200 ppm 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001).
STEL: 885 mg/m3 15 minute(s). Form: All forms.
STEL: 300 ppm 15 minute(s). Form: All forms.
TWA: 590 mg/m3 10 hour(s). Form: All forms.
TWA: 200 ppm 10 hour(s). Form: All forms.
OSHA PEL (United States, 8/1997).
TWA: 590 mg/m3 8 hour(s). Form: All forms.
TWA: 200 ppm 8 hour(s). Form: All forms.
Stoddard Solvent ACGIH TLV (United States, 1/2005).
TWA: 525 mg/m3 8 hour(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001).
CEIL: 1800 mg/m3 15 minute(s). Form: All forms.
TWA: 350 mg/m3 10 hour(s). Form: All forms.
OSHA PEL (United States, 8/1997).
TWA: 2900 mg/m3 8 hour(s). Form: All forms.
TWA: 500 ppm 8 hour(s). Form: All forms.
Solvent naphtha (petroleum), light aromatic Manufacturer (United States).
TWA: 40 ppm 8 hour(s). Form: All forms.
Canada
Product name Exposure limits
Toluene ACGIH TLV (United States, 1/2005). Skin
TWA: 188 mg/m3 8 hour(s). Form: All forms.
TWA: 50 ppm 8 hour(s). Form: All forms.
Titanium dioxide ACGIH TLV (United States, 1/2005).
TWA: 10 mg/m3 8 hour(s). Form: All forms.
Xylene ACGIH TLV (United States, 1/2005).
STEL: 651 mg/m3 15 minute(s). Form: All forms.
STEL: 150 ppm 15 minute(s). Form: All forms.
TWA: 434 mg/m3 8 hour(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
Heptan-2-one ACGIH TLV (United States, 1/2005).
TWA: 233 mg/m3 8 hour(s). Form: All forms.
TWA: 50 ppm 8 hour(s). Form: All forms.
Ethylbenzene ACGIH TLV (United States, 1/2005).
STEL: 125 ppm 15 minute(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
Carbon Black ACGIH TLV (United States, 1/2005).
TWA: 3.5 mg/m3 8 hour(s). Form: All forms.
Methyl ethyl ketone ACGIH TLV (United States, 1/2005).
STEL: 885 mg/m3 15 minute(s). Form: All forms.
STEL: 300 ppm 15 minute(s). Form: All forms.
TWA: 590 mg/m3 8 hour(s). Form: All forms.
TWA: 200 ppm 8 hour(s). Form: All forms.
Stoddard Solvent ACGIH TLV (United States, 1/2005).
TWA: 525 mg/m3 8 hour(s). Form: All forms.
TWA: 100 ppm 8 hour(s). Form: All forms.
Solvent naphtha (petroleum), light aromatic Manufacturier (Canada).
TWA: 40 ppm 8 hour(s).
Date of issue : 11/15/2006 Page: 5/11
DAR
Mexico
Product name Exposure limits
Toluene NOM-010-STPS (Mexico, 9/2000). Skin
CPT: 188 mg/m3 8 hour(s). Form: All forms.
CPT: 50 ppm 8 hour(s). Form: All forms.
Titanium dioxide NOM-010-STPS (Mexico, 9/2000).
CCT: 20 mg/m3 15 minute(s). Form: All forms.
CPT: 10 mg/m3 8 hour(s). Form: All forms.
Xylene NOM-010-STPS (Mexico, 9/2000).
CCT: 655 mg/m3 15 minute(s). Form: All forms.
CCT: 150 ppm 15 minute(s). Form: All forms.
CPT: 435 mg/m3 8 hour(s). Form: All forms.
CPT: 100 ppm 8 hour(s). Form: All forms.
Heptan-2-one NOM-010-STPS (Mexico, 9/2000).
CCT: 465 mg/m3 15 minute(s). Form: All forms
CCT: 100 ppm 15 minute(s). Form: All forms
CPT: 235 mg/m3 8 hour(s). Form: All forms
CPT: 50 ppm 8 hour(s). Form: All forms
Ethylbenzene NOM-010-STPS (Mexico, 9/2000).
CCT: 545 mg/m3 15 minute(s). Form: All forms
CCT: 125 ppm 15 minute(s). Form: All forms
CPT: 435 mg/m3 8 hour(s). Form: All forms
CPT: 100 ppm 8 hour(s). Form: All forms
Carbon Black NOM-010-STPS (Mexico, 9/2000).
CCT: 7 mg/m3 15 minute(s). Form: Smoke
CPT: 3.5 mg/m3 8 hour(s). Form: Smoke
Methyl ethyl ketone NOM-010-STPS (Mexico, 9/2000).
CCT: 885 mg/m3 15 minute(s). Form: All forms.
CCT: 300 ppm 15 minute(s). Form: All forms.
CPT: 590 mg/m3 8 hour(s). Form: All forms.
CPT: 200 ppm 8 hour(s). Form: All forms.
Stoddard Solvent NOM-010-STPS (Mexico, 9/2000).
CCT: 1050 mg/m3 15 minute(s). Form: All forms.
CCT: 200 ppm 15 minute(s). Form: All forms.
CPT: 523 mg/m3 8 hour(s). Form: All forms.
CPT: 100 ppm 8 hour(s). Form: All forms.
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor or
mist, use process enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
Personal protection
Eyes : Splash goggles.
Skin : Synthetic apron.
Respiratory : Vapor respirator.
Hands : Nitrile gloves.
HMIS Code/Personal : J
protective equipment
Personal protection in case : Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-
of a large spill approved self-contained breathing apparatus or equivalent and full protective gear.
Date of issue : 11/15/2006 Page: 6/11
DAR
Hygiene measures : Wash hands, forearms and face thoroughly after handling compounds and before eating,
smoking and using the lavatory and at the end of the day. Follow good industrial hygiene
practice.
9 . Physical and chemical properties
Physical state : Liquid. (Aerosol.)
Flash point : Closed cup: 10°C (50°F).(Pensky-Martens.)
Auto-ignition temperature : The lowest known value is 232.22°C (450°F) (Stoddard Solvent).
Flammable limits : Lower: 1.2%
Odor : Solvent.
Boiling/condensation point : 77.8 to 203.9°C (172 to 399°F)
Melting/freezing point : Weighted average: -64.57°C (-84.2°F)
Critical temperature : The lowest known value is 262.6°C (504.7°F) (Methyl ethyl ketone).
Relative density : 1.062 (Water = 1)
Vapor pressure : 0.9 kPa (7.1 mm Hg) (at 20°C)
Vapor density : >1 (Air = 1)
Volatility : 54 to 63% (v/v)
Odor threshold : Weighted average: 3.54 ppm
Evaporation rate : 78
VOC : 59 (%)
Solubility : Partially soluble in diethyl ether.
Insoluble in cold water, hot water.
10 . Stability and reactivity
Stability and reactivity : The product is stable.
Incompatibility with various : Reactive with oxidizing materials, acids and alkalis.
substances
Hazardous decomposition : These products are halogenated compounds, hydrogen fluoride.
products
Hazardous polymerization : Will not occur.
Conditions of reactivity : Extremely flammable in the presence of the following materials or conditions: open
flames, sparks and static discharge.
Highly flammable in the presence of the following materials or conditions: heat.
Flammable in the presence of the following materials or conditions: shocks and
mechanical impacts.
11 . Toxicological information
Toxicity data
Product/ingredient name Test Result Route Species
Toluene LD50 636 mg/kg Oral Rat
LD50 1221 mg/kg Dermal Rabbit
Xylene LD50 4300 mg/kg Oral Rat
LD50 2119 mg/kg Oral Mouse
LD50 >1700 mg/kg Dermal Rabbit
LC50 6350 ppm (4 hour(s)) Inhalation Rat
Heptan-2-one LD50 1670 mg/kg Oral Rat
LD50 730 mg/kg Oral Mouse
LD50 10220 mg/kg Dermal Rabbit
LC50 >2000 ppm (4 hour(s)) Inhalation Rat
LC50 15400 mg/kg Oral Rat
Date of issue : 11/15/2006 Page: 7/11
DAR
Methyl ethyl ketone LD50 2737 mg/kg Oral Rat
LD50 4050 mg/kg Oral Mouse
LD50 6480 mg/kg Dermal Rabbit
Solvent naphtha (petroleum), light aromatic LD50 8400 mg/kg Oral Rat
Acute Effects
Eyes : Irritating to eyes.
Skin : Irritating to skin. May cause sensitization by skin contact. May be harmful if absorbed
through skin.
Inhalation : Harmful by inhalation. Irritating to respiratory system.
Ingestion : Harmful if swallowed.
Potential chronic health : Carcinogenic effects: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3
effects (Not classifiable for humans.) by IARC [Toluene]. Classified 2B (Possible for humans.) by
IARC [Titanium dioxide]. Classified None. by NIOSH [Titanium dioxide]. Classified A4 (Not
classifiable for humans or animals.) by ACGIH [Titanium dioxide]. Classified A4 (Not
classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC
[Xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by
IARC [Ethylbenzene]. Classified None. by NIOSH [Ethylbenzene]. Classified + (Proven.)
by NIOSH [Carbon Black]. Classified 2B (Possible for humans.) by IARC [Carbon Black].
Classified A4 (Not classifiable for humans or animals.) by ACGIH [Carbon Black].
Mutagenic effects Not available.
:
Teratogenic effects: Not available.
Target organs : Contains material which causes damage to the following organs: blood, kidneys, lungs,
liver, peripheral nervous system, gastrointestinal tract, upper respiratory tract, skin, central
nervous system (CNS), eye, lens or cornea, nose/sinuses, throat.
Special remarks on chronic : Embryotoxic and/or fetotoxic in animals. (Xylene)
effects on humans
12 . Ecological information
Ecotoxicity data
Product/ingredient name Species Period Result
Toluene Daphnia magna (EC50) 48 hour(s) 6 mg/l
Daphnia magna (EC50) 48 hour(s) 6.56 mg/l
Oncorhynchus mykiss (EC50) 48 hour(s) 6.78 mg/l
Oncorhynchus mykiss (LC50) 96 hour(s) 5.8 mg/l
Oncorhynchus mykiss (LC50) 96 hour(s) 6.78 mg/l
Pimephales promelas (LC50) 96 hour(s) 12.6 mg/l
Titanium dioxide Daphnia magna (EC50) 48 hour(s) >1000 mg/l
Xylene Oncorhynchus mykiss (LC50) 96 hour(s) 3.3 mg/l
Oncorhynchus mykiss (LC50) 96 hour(s) 8.2 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 8.6 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 12 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 13.3 mg/l
Pimephales promelas (LC50) 96 hour(s) 13.4 mg/l
Heptan-2-one Pimephales promelas (LC50) 96 hour(s) 131 mg/l
Ethylbenzene Daphnia magna (EC50) 48 hour(s) 2.93 mg/l
Daphnia magna (EC50) 48 hour(s) 2.97 mg/l
Selenastrum capricornutum 48 hour(s) 7.2 mg/l
(EC50)
Oncorhynchus mykiss (LC50) 96 hour(s) 4.2 mg/l
Pimephales promelas (LC50) 96 hour(s) 9.09 mg/l
Poecilia reticulata (LC50) 96 hour(s) 9.6 mg/l
Methyl ethyl ketone Daphnia magna (EC50) 48 hour(s) 5091 mg/l
Pimephales promelas (LC50) 96 hour(s) 3220 mg/l
Environmental precautions : No known significant effects or critical hazards.
Date of issue : 11/15/2006 Page: 8/11
DAR
Products of degradation : These products are carbon oxides and water, halogenated compounds. Some metallic
oxides.
Toxicity of the products of : The products of degradation are as toxic as the product itself.
biodegradation
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Avoid
dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.
Disposal of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
and local authority requirements.
14 . Transport information
NAERG : 126
Regulatory Proper shipping name Class UN number PG Label
information
UN / IMDG / IATA AEROSOLS, FLAMMABLE, N.O.S. (each not 2.1 UN1950 -
Classification exceeding 1 L capacity) (Difluoroethane,
Toluene) 2
DOT Classification AEROSOLS, FLAMMABLE, N.O.S. (each not 2.1 UN1950 -
exceeding 1 L capacity) (Difluoroethane, FLAMMABLE GAS
Toluene) 2
TDG Classification AEROSOLS, FLAMMABLE, N.O.S. (each not 2.1 UN1950 -
exceeding 1 L capacity) (Difluoroethane,
Toluene) 2
15 . Regulatory information
United States
HCS Classification : Flammable aerosol.
Pressure hazard
Toxic material
Irritating material
Sensitizing material
Carcinogen
Target organ effects
U.S. Federal regulations : TSCA : All components listed.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Titanium dioxide; Xylene; Heptan-2-one;
Difluoroethane; Ethylbenzene; Carbon
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